Journal
TETRAHEDRON
Volume 62, Issue 4, Pages 594-604Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2005.10.014
Keywords
total synthesis; lamellarin; Hinsberg reaction; Suzuki-Miyaura coupling
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Total synthesis of cytotoxic marine alkaloids, lamellarins D, L, and N, has been achieved by using Hinsberg-type pyrrole synthesis and palladium-catalyzed Suzuki-Miyaura coupling of the 3,4-dihydroxypyrrole bistriflate 6 as the key reactions. The total yields of lamellarins D, L, and N from the common intermediate 6 are 54, 58, and 50%, respectively. (c) 2005 Elsevier Ltd. All rights reserved.
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