Journal
CHEMISTRY OF MATERIALS
Volume 18, Issue 2, Pages 367-373Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cm0518527
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We demonstrated that nanotubes synthesized from a NaOH treatment on TiO2 with subsequent acid washing could proceed with repeatable crystalline-structure transformation through a simple acid-base washing step. By providing the unit cell parameters, we identified a divalent salt titanate (Na2Ti2O5 center dot H2O) with a layered structure as the structure formed after the NaOH treatment. With the increase in acidity during the post-treatment acid washing, the layered titaniate transformed into a nanotube through Na+-H+ substitution, and eventually transformed into anatase TiO2. Crystalline-structure analysis has shown the feasibility of this titanate-titania transformation occuring through a simple structural rearrangement. A complete scheme for the formation and transformation of nanotubes induced by the NaOH treatment and the post-treatment washing was proposed.
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