Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 128, Issue 3, Pages 898-904Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja0558995
Keywords
-
Categories
Funding
- NIGMS NIH HHS [GM 46059] Funding Source: Medline
Ask authors/readers for more resources
The treatment of bis(2-(dicyclohexylphosphino)-2',6'-dimethoxybiphenyl)PdCl2 with AgBF4 produces an air-stable phosphine/arene-ligated Pd(I) dimer with two seemingly identical Pd-arene interactions by X-ray crystallography. However, NMR and theoretical electron topographical analyses of this complex distinguish between these two interactions. One interaction is classified as an arenium-like complex, while the other is classified as a,pi-interaction. Additionally, this complex is a suitable precatalyst for high yielding Suzuki-Miyaura coupling reactions in short reaction times.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available