Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 110, Issue 3, Pages 1288-1293Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp055910n
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3,8-Bis-hexadecyloxy-benzo[c]cinnoline (BBC16) self-assembled into two structures at highly oriented pyrolytic graphite (HOPG) surface: one was formed by molecules with a V-like configuration (C-2v symmetry) and the other by molecules with a Z-like configuration (C-s symmetry). The self-assembled structures could be tweaked by the solvents used. In the self-assembled monolayers (SAMs) on HOPG, the BBC16 molecule adopted the V-like configuration in polar solvents and the Z-like configuration in nonpolar solvents. Moreover, the solvent viscosity, solvent dissolvability of BBC16, and substrate temperature also played some roles in tuning the two-dimensional self-assembled structures.
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