Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 110, Issue 3, Pages 1099-1101Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp0563538
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We report excess hydrogen saturation values from high-pressure isotherms of metal organic framework structures taken at 77 K. Zn benzendicarboxylate (IRMOF-1) and Zn naphthalendicarboxylate (IRMOF-8) linker structures show identical saturation values of 137 hydrogen molecules on a per unit cell basis, despite the higher sorption potential of IRMOF-8 of 6.1 kJ/mol over that of IRMOF-1 of 4.IkJ/mol. Charge transfer between linker and vertex, as well as surface area, appear to dominate the sorption behavior, over that of linker length in these two systems.
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