Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2006, Issue 3, Pages 577-581Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200500738
Keywords
supported catalysts; alkenes; supercritical carbon dioxide; olefin metathesis; ruthenium
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We describe RCM reactions in the presence of a Hoveydatype catalyst covalently immobilized on different support materials. The performance of the catalyst was highly dependent on the nature of the support, and in some cases high levels of conversion were obtained, allowing for repetitive cycles. In addition, remarkably low levels of leaching of ruthenium. into the product (20 ppm) were observed. This environmentally benign process has potential for continuous applications. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)
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