4.4 Article

Chiral bisphospholane ligands (Me-ketalphos): synthesis of their Rh(I) complexes and applications in asymmetric hydrogenation

Journal

TETRAHEDRON
Volume 62, Issue 5, Pages 868-871

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2005.10.047

Keywords

hydrogenation; catalyst; rhodium

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Rhodium complexes of functionalized bisphospholane ligands (S,S,S,S-Me-ketalphos) 1 and (R,S,S,R-Me-ketalphos) 2 have been used as catalyst precursors for the asymmetric hydrogenation of several different types of functionalized olefins and have achieved high enantioselectivities. (c) 2005 Elsevier Ltd. All rights reserved.

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