Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 348, Issue 3, Pages 313-316Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200505389
Keywords
catalytic oxidation; glucose oxidation; gold; hydrogen peroxide; oxygen
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Careful analytical determinations show that the gold-catalysed aerobic oxidation of glucose occurs through a two-electrons mechanism leading to gluconate and hydrogen peroxide. This latter decomposes before reaching the critical concentration for competing with O-2 in glucose oxidation. A mechanism of glucose oxidation on gold nanoparticles is presented.
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