Journal
PURE AND APPLIED CHEMISTRY
Volume 78, Issue 2, Pages 351-361Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1351/pac200678020351
Keywords
palladium; tandem reactions; cyclization; coupling; indole; heterocycles; direct arylation
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Several Pd-catalyzed cyclization methods were developed, including norbornene-mediated Catellani-type reactions, a Pd-catalyzed coupling reaction of aryl iodides and allyl moieties, and a tandem C-N/C-C coupling of gem-dihalovinyl systems. These ring-forming methods were applied to the synthesis of highly functionalized carbocyclic and heterocyclic compounds. Intermolecular Pd-catalyzed methods for synthesis of highly substituted arene compounds were also developed.
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