Journal
ELECTROPHORESIS
Volume 27, Issue 3, Pages 650-660Publisher
WILEY
DOI: 10.1002/elps.200500470
Keywords
cylindrical capillary; electroosmosis; liquid displacement; stepwise pulse regime; velocity profiles
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A theoretical model of the EOF established in a wide capillary after the application of a stepwise voltage has been developed. Both periodical and aperiodical flow regimes were studied with arbitrary pulse/pulse or pulse/pause durations and amplitudes. The numerical analysis performed for a few types of periodical regimes showed the peculiarities of the profiles of liquid velocity and its displacement both for the transition to the stationary regime and for the quasi-stationary periodical and aperiodical regimes.
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