Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 244, Issue 1-2, Pages 110-117Publisher
ELSEVIER
DOI: 10.1016/j.molcata.2005.08.045
Keywords
asymmetric catalysis; heterogeneous catalysis; enantioselective Henry reaction; BINOL-MCM-4 1; MCM-41 as support; silica as support
Categories
Ask authors/readers for more resources
A chiral BINOL ligand covalently anchored on silica and mesoporous MCM-41 was synthesized and characterized by powder XRD, FT-IR, N-2 adsorption-desorption measurements, TGA and elemental analysis. These anchored ligands were then used to prepare La-Li-BINOL-silica la and La-Li-BINOL-MCM-41 1b complexes. The immobilized catalysts having lanthanum content around 0.12-0.18 mmol/g were tested as enantioselective catalyst for Henry reaction and ee 55-84% were found which were comparable to its homogeneous counterpart. The solid catalysts can be reused by simple filtration and recycled several times without much loss in performance. (c) 2005 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available