Journal
ORGANIC LETTERS
Volume 8, Issue 3, Pages 395-398Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol052578p
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A highly regioselective amination of 6-aryl-2,4-dichloropyrimidine with aliphatic secondary amines and aromatic amines has been developed which strongly favors the formation of the C4-substituted product. The reactions with aliphatic amines are carried out using LiHMDS as the base and are catalyzed by Pd, while the aromatic amines require no catalyst.
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