Journal
APPLIED CATALYSIS A-GENERAL
Volume 301, Issue 1, Pages 79-88Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcata.2005.11.015
Keywords
allylic oxidation; copper-complex; cyclohexene oxidation; immobilization; peroxides; Schiff base
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Allylic oxidation of cyclohexene was carried Out over a Schiff base copper complex and its immobilized analogue supported on organically modified silica, The immobilized complex has been characterized by using atomic absorption spectrophotometry (AAS), FT-IR, EPR and UV-vis spectroscopic studies and SEM image analysis. The catalytic oxidation of cyclohexene was carried Out over this copper complex and the immobilized analog with different oxidants like dilute aqueous hydrogen peroxide and terf-butyl hydroperoxide at ambient conditions. Acetonitrile and water was used as solvent and dispersion medium, respectively, with or without additional acid in different sets of oxidation reactions. 2-Cyclohexen-1-one was obtained its the major product with small amounts of cyclohexene oxide, 2-cyclohexen-l-ol and 1,2-cyclohexane-diol. The activity of the immobilized catalyst remains nearly the same after two cycles, Suggesting the true heterogeneous nature of the catalyst. (c) 2005 Elsevier B.V. All rights reserved.
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