4.4 Article

Cationic Au(I)-catalyzed cycloisomerization of aromatic enynes for the synthesis of substituted naphthalenes

Journal

SYNLETT
Volume -, Issue 3, Pages 411-414

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-2006-926261

Keywords

cycloisomerization; catalysis; enynes; gold; indenes; naphthalenes

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A cationic Au(I) complex catalyzed the cycloisomerization of aromatic enynes that possess a substituent on their alkyne terminus. Cyclization of the 6-endo-dig type proceeded dominantly to give 1,3-di- and 1,2,3-tri substituted naphthalenes.

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