Journal
SYNTHESIS-STUTTGART
Volume -, Issue 4, Pages 692-698Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2006-926305
Keywords
chlorides; water; palladium; cross-coupling; biaryls
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Aryl chlorides are efficiently coupled with aryl boronic acids using ligandless Pd/C in water. The catalyst is easily recovered via filtration and reused up to four times with an overall yield of 73%. In addition the catalytic activity and selectivity of a variety of homogeneous and heterogeneous palladium sources have been compared.
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