Determination of atrazine and simazine in environmental water samples using multiwalled carbon nanotubes as the adsorbents for preconcentration prior to high performance liquid chromatography with diode array detector

Multiwalled carbon nanotubes, a new nanoscale material, has been gained many interests for use in various fields, and has exhibited exceptional merit as SPE absorbents for enrichment of environmental pollutants. This paper focused on the enriching power of atrazine and simazine, two important widely used triazine herbicides and described a novel and sensitive method for determination of these two herbicides based on SPE using multiwalled carbon nanotubes as solid phase absorbents followed by high performance liquid chromatography with diode array detector. Factors that maybe affect the enrichment efficiency of multiwalled carbon nanotubes such as the volume of eluent, sample flow rate, sample pH, and volume of the water samples were optimized. Under the optimal procedures, multiwalled carbon nanotubes as the absorbents have obtained excellent enrichment efficiency for atrazine and simazine. The detection limits of the atrazine and simazine were 33 and 9 ng l(-1), respectively. The spiked recoveries of the two analytes were over the range of 82.6-103.7% in most cases. Good analytical performance was achieved from real-world water samples such as river water, reservoir water, tap water and wastewater after primary pretreatment with proposed method. All these experimental results indicated that the developed method could be used as an alternative for the routine analysis of atrazine and simazine in many real water samples. (c) 2005 Published by Elsevier B.V.