Organometallic modification approach to the control of push-pull architectures:: Synthesis, properties and radical polymerization of chromium N-vinylcarbazole derivatives

In an effort to combine the donor character of the carbazole unit with the electron-withdrawing nature of the chromiumtricarbonyl moiety, which can be further modified by exchange of the CO ligand, a new series of vinyl-type monomers with organometallic push-pull chromophores, (N-vinylcarbazole)Cr(CO)(2)L (L = CO (2), PPh3 (4), (C3H5)+BF4- (5)) and (N-vinylcarbazole)bisCr(CO)(3) (3), have been synthesized and isolated, wherein 2 could be converted into 3 under appropriate conditions. All compounds were characterized spectroscopically, and X-ray crystal structure analyses were performed for 2-4. The coordination-induced geometrical changes occur predominantly on the N-center and its attached double bond. PPh3 replaces a CO group leading to the N-vinyl double bond length shortening from 1.274 (12) to 1.245 (9) angstrom. The distance of Cr from the carbazole plane, which allows estimates of the strength of the metal-ligand pi-bonding, is shorter in 3 than in 2 as a result of an electronic communication between the two Cr(CO)(3) groups on each aryl ring of carbazole molecule. Electronic absorption and fluorescence spectral features of these complexes have been studied in terms of the electronic nature of the ligands. The change from 2 to 3 causes a subtle red-shift of the absorption bands due to the electronic transitions within dinuclear-carbazole ring system. The polymerization studies of these complexes under free-radical conditions lead to a better understanding of how the organometallic moiety affects the vinyl polymerization. The intriguing effect of the organometallic moiety on the intrachain excimer formation in the resultant polymers have been shown to be likely. (c) 2005 Elsevier B.V. All rights reserved.