Journal
ORGANIC LETTERS
Volume 8, Issue 4, Pages 769-772Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol053050n
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A highly active chiral 4-aminopyridine nucleophilic catalyst, available in three steps from (S,S)-hexane-2,5-diol, was applied to the asymmetric Steglich rearrangement of O-aceylated azlactones (1 mol % loading, up to 76% ee).
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