Journal
ORGANIC LETTERS
Volume 8, Issue 4, Pages 677-679Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol052871p
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The first enantioselective total synthesis of convolutamydines B and E has been achieved using our vinylogous Mukaiyama aldol reaction. The synthesis features highly diastereoselective vinylogous Mukaiyama aldol reaction with isatin instead of aldehydes to construct a chiral center of convolutamydines. Additionally, the absolute configuration of natural convolutamydine B has been determined as R by its CD spectrum.
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