Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 71, Issue 4, Pages 1633-1639Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo052399l
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2,2-[60]Fullerenoalkanoyl chlorides (1a-d) were easily and securely prepared from the corresponding 2,2-[60]fullerenoalkanoic acids (2a-d) by the reaction with thionyl chloride in an unusual mixed solvent, CH2O2/dioxane. The characterization of 1a-d by H-1 and C-13 NMR, FT-IR, and MALDI-TOF-MASS was conducted for the first time. The 2,2-[60]fullerenoalkanoyl chlorides thus obtained were readily converted to the corresponding amides and esters in moderate to excellent yields by the condensation with amines and alcohols, respectively. Upon applying the condensation, [60]fullerene-biomolecule hybrids were easily prepared.
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