Journal
INORGANIC CHEMISTRY
Volume 45, Issue 4, Pages 1508-1516Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic050999x
Keywords
-
Categories
Ask authors/readers for more resources
Two novel three-dimensional complexes formulated as [M(3)(bime)(2)(mu(3)-OH)(2)(HO-BDC)(2)](n) (M = Co, 1; Cu, 2) [bime = 1,2-bis(imidazol-1'-yl)ethane, HO-H(2)BDC = 5-hydroxyisophthalic acid] have been hydrothermally synthesized and characterized. Both 1 and 2 exhibit similar structural frameworks resulting from one-dimensional metal/oxygen chains extended by HO-BDC, but the bridging modes of HO-BDC and coordination environments of metal centers are different. Complexes 1 and 2 crystallize in the orthorhombic system, space group Pbcn, a = 18.458(2) [18.2119(12) for 2] angstrom, b = 12.0616(14) [11.6847(7)] angstrom, c = 11.4859(14) [12.0688(6)] angstrom, and Z = 4 (4). Magnetic studies show that 1 displays a slow magnetic relaxation, a large hysteresis, and distinct finite-size effects and 2 contains an antiferromagnetic chain.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available