4.7 Article

New disordering mode for TFSI- anions:: The nonequilibrium, plastic crystalline structure of Et4NTFSI

Journal

INORGANIC CHEMISTRY
Volume 45, Issue 4, Pages 1412-1414

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic0513742

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A new TFSI- anion disordering mode has been discovered in a supercooled plastic crystalline phase of Et4NTFSI, which may, in part, account for the low melting points of TFSI- salts with organic cations, thereby forming ionic liquids, and the intriguing properties of LiTFSI for lithium battery applications.

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