4.7 Article

a new method for the synthesis of Z-enediones via IBX-mediated oxidative rearrangement of 2-alkynyl alcohol systems

Journal

CHEMICAL COMMUNICATIONS
Volume -, Issue 7, Pages 764-766

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b515838a

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o-Iodoxybenzoic acid (IBX) was found to mediate the conversion of alpha-alkynyl alcohols into Z-enediones under notably mild conditions via a novel rearrangement mechanism (33-65% yield, 13 examples).

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