4.5 Article

Total syntheses of oxygenated brazanquinones via regioselective homologous anionic fries rearrangement of benzylic O-carbamates

Journal

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 2, Issue -, Pages -

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BEILSTEIN-INSTITUT
DOI: 10.1186/1860-5397-2-1

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Using new variations of anionic aromatic chemistry, the total synthesis of oxygenated brazanquinones (1a-1c), derived from beta-brasan, a natural product isolated from Caesalpina echinata, via carbamates 2a-2c is described.

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