Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 110, Issue 7, Pages 3066-3070Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp0553380
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A new and facile route is reported to manipulate the self-assembly synthesis of hierarchically ordered Rb-OMS-2 and pyrolusite with an interesting flowerlike morphology by a direct and mild reaction between rubidium chromateand manganese sulfate without any organic templates. The crystal forms, morphologies, and tunnel sizes of the obtained OMS materials can be controlled. A mechanism for the growth of manganese dioxides with flowerlike architectures was proposed. The obtained products exhibit potential for use in catalysis and other applications.
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