Journal
MACROMOLECULAR RAPID COMMUNICATIONS
Volume 27, Issue 4, Pages 238-241Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.200500793
Keywords
cyclodextrin; hydrogel; inclusion chemistry; molecular recognition; redox-responsiveness
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We have successfully constructed a redox-responsible hydrogel system by combination of beta-cyclodextrin (beta-CD), dodecyl-modified poly(acrylic acid) [p(AA/ C-12)] and a redox-responsive guest, ferrocenecarboxylic acid (FCA). In the reduced state of FCA, the ternary mixture exhibited a gel-like behavior, whereas, in its oxidized state, the mixture exhibited a sol behavior.
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