Journal
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
Volume 418, Issue 1-2, Pages 199-210Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.msea.2005.11.052
Keywords
wet impregnation; infiltration; cathode; anode; solid oxide fuel cell
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Development of solid oxide fuel cells (SOFC) for operation at intermediate temperatures of 600-800 degrees C with hydrocarbon fuels requires a cathode and anode with high electrocatalytic activity for O-2 reduction and direct oxidation of hydrocarbon fuels, respectively. Wet impregnation is a well known method in the development of heterogeneous catalysts. Surprisingly, very few have concentrated on the application of the wet impregnation technique to deposit nano-sized particles into the established electrode structure of the SOFC. This paper reviews and discusses the progress in the application of the wet impregnation technique in the development of Ni-free Cu-based composite anodes, doped CeO2-impregnated (La, Sr)MnO3 (LSM) cathodes and Ni anodes, CO(3)Oy(4)-infiltrated cathodes and precious metal-impregnated electrodes. Enhancement in the electrode microstructure and cell performance is substantial, showing the great potential of the wet impregnation method in the development of high performance and nano-structured electrodes with specific functions. However, the long-term stability of the impregnated electrode structure needs to be addressed. (c) 2005 Elsevier B.V. All rights reserved.
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