Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2006, Issue 5, Pages 1166-1176Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200500826
Keywords
ring-closing metathesis; cyclic amino acids; vinyl fluoride; fluorinated heterocycles; fluoroacrylates
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The synthesis of highly functionalized fluorinated piperidines is described. The key step in this synthesis is a ring-closing metathesis reaction involving fluoride-substituted olefins, which leads to the corresponding cyclic vinyl fluorides. Several sequences to arrive at differently substituted piperidines have been evaluated. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006).
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