Journal
TETRAHEDRON
Volume 62, Issue 9, Pages 2045-2049Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2005.09.152
Keywords
fullerene; C-60; cyclodextrin; conjugate; rhodamine B
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Two beta-cyclodextrin-C-60 conjugates (3 and 4) with a flexible linker at the secondary face of cyclodextrin are synthesized by a single reaction of 2-(omega-azidoundecanyl)-2-O-heptakis (2,3,6-tri-O-methyl)-beta-cyclodextrin (2) and C-60, both of which display satisfactory water solubility. Structural analyses show that 3 is a closed [5,6] aziridinofullerene, whereas 4 is a bis-adduct derivative. Using rhodamine B (RhB) as a guest molecule, the inclusion complexation behavior of 3 was investigated in aqueous solution. (c) 2005 Elsevier Ltd. All rights reserved.
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