Journal
JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING
Volume 41, Issue 3, Pages 315-328Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/10934520500423196
Keywords
advanced oxidation processes; azo dyes; CI Acid Red 14; Fenton's reagent; photo-Fenton reaction; ferrioxalate; photooxidation
Categories
Ask authors/readers for more resources
The decolorization of the solution containing a common textile and leather dye, C.I. Acid Red 14 (AR14), at pH 3 by hydrogen peroxide photolysis, Fenton, Fenton-like and photo-Fenton processes was studied. The dark and light reactions were carried out in stirred batch photoreactor equipped with an UV-C lamp (30 W) as UV light source. The experiments showed that the dye was resistant to the UV illumination, but was oxidized when one of Fe(II), Fe(III) and H2O2 compounds was present. It was also found that UV light irradiation can accelerate significantly the rate of AR14 decolorization in the presence of Fe(III)/H2O2 or Fe(II)/H2O2, comparing to that in the dark. The effect of different system variables like initial concentration of the azo dye, effect of UV light irradiation, initial concentration of Fe(II) or Fe(III) and added oxalate ion has been investigated. The results showed that the decolorization efficiency of AR14 at the reaction time of 2 min follows the decreasing order: UV/H2O2/Fe(III)/oxalate > UV/H2O2/Fe(III) > UV/H2O2/Fe(II) > UV/H2O2. Our results also showed that the UV/H2O2 /Fe(III)/oxalate process was appropriate as the effective treatment method for decolorization of a real dyeing and finishing. The mechanism for each process is also discussed and linked together for understanding the observed differences in reactivity.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available