4.7 Article

Investigation of evaporation and biodegradation of fuel spills in Antarctica: II - Extent of natural attenuation at Casey Station

Journal

CHEMOSPHERE
Volume 63, Issue 1, Pages 89-98

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.chemosphere.2005.07.040

Keywords

GC-FID; fingerprinting; petroleum hydrocarbons; special Antarctic blend; diesel; weathering

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In many temperate regions, fuel and oil spills are sometimes managed simply by allowing natural degradation to occur, while monitoring soils and groundwater to ensure that there is no off-site migration or on-site impact. To critically assess whether this approach is suitable for coastal Antarctic sites, we investigated the extent of evaporation and biodegradation at three old fuel spills at Casey Station. Where the contaminants migrated across frozen ground, probably beneath snow, approximately half the fuel evaporated in the first few months prior to infiltration at the beginning of summer. Once in the ground, however, evaporation rates were negligible. In contrast, minor spills from fuel drums buried in an abandoned waste disposal site did not evaporate to the same extent. Biodegradation within all three spill sites is generally very minor. We conclude that natural attenuation is not a suitable management strategy for fuel-contaminated soils in Antarctic coastal regions. (c) 2005 Published by Elsevier Ltd.

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