Journal
JOURNAL OF SOLID STATE CHEMISTRY
Volume 179, Issue 3, Pages 824-829Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2005.12.005
Keywords
open-framework; crystal structure; hydrothermal synthesis; gallium phosphite; organic template
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Ga-3(HPO3)(4)F-4(H(3)DETA) is a new open-framework fluorinated gallium phosphite obtained by mild hydrothermal synthesis using diethylenetriamine as templated agent and characterized by single crystal X-ray diffraction, the powder X-ray diffraction, IR spectroscopy, TGA, ICP and elemental analyses. It crystallizes in the monoclinic space group C2/c, a = 12.741(6) angstrom, b = 12.068(6)angstrom, c = 11.988(5) angstrom, beta = 94.902(8)degrees, V = 1836.6(15) angstrom(3), Z = 4. The construction of 3D open-framework structure in the title compound may be viewed as the assembly of pentameric building units and HPO3 groups. The pentameric building unit is the first to be found, which lead to form the three types of channels along a-, b- and c-axes, respectively, in gallium phosphite. The triprotonated DETA cations are inserted within the 10-membered ring channels and interact with anions of the framework via hydrogen bonds. (C) 2005 Elsevier Inc. All rights reserved.
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