Journal
INORGANICA CHIMICA ACTA
Volume 359, Issue 4, Pages 1193-1199Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2005.09.005
Keywords
Copper(II)-azido complex; dimer; DFT; magnetic properties; X-ray crystal structure
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A new rare variety asymmetric mu(2)-1,1-azido bridged copper(II) complex has been synthesized and characterized structurally and magnetically. The complex [Cu2L2(mu(2)-1,1-N-3)(2)]center dot H2O center dot CH3OH (L = 1-(N-ortho-hydroxyacetophenimine)-2-aminoethane) (1), crystallizes in monoclinic space group, P2(1)/n, with a = 9.469(4) angstrom, b = 12.526(8) angstrom, c = 12.899(10) angstrom, beta = 105.79(6)degrees, V = 1472.2(16) angstrom(3). X-ray study reveals that he Cu-N(azide)-Cu angles in this complex is 90.4 degrees. This is unusually low in comparison to that of the same angle in other end-on azido-bridged binuclear complexes. Though a strong ferromagnetic interaction between the metal centers is expected in the complex, the coupling has actually been found to be anti ferromagnetic (J = -4.2 cm(-1)), instead. To rationalize this paradoxical magnetic behavior, DFT calculation of this and other four complexes with very similar structure have been performed within broken symmetry framework. The calculated magnetic coupling constants (J) are in excellent agreement, both in sign and in the magnitude of the exchange interaction, with the experimental data, and the spin density map is correctly reproduced. (c) 2005 Elsevier B.V. All rights reserved.
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