Journal
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
Volume 10, Issue 3, Pages 157-167Publisher
SPRINGER
DOI: 10.1007/s10008-005-0058-y
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The advantages of corrected Marcus plots as compared to the more traditional corrected Tafel plots are discussed and illustrated by the treatment of experimental data. The procedures are proposed to avoid the uncertainties of EDL correction and to estimate the reliable values of transmission coefficient and total reorganization energy. Special emphasis is placed on the diagnostics of activationless reactions in frames of the same method.
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