Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 9, Issue 3, Pages 277-280Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2005.11.020
Keywords
5-fluorouracil-1-acetate; lead(II); 2D coordination polymer; lone pair
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A novel 2D polymeric Pb-II complex containing the first Pb-O=, bond, [Pb(5-FUOAc)(2)](n) (5-FUOAc = 5-fluorouracil-1-acetate), has been synthesized and characterized. The single-crystal X-ray data shows the coordination number in Pb-II ions is seven, PbO7, with stereo-chemically active electron lone pairs, and the coordination sphere is hemidirected. (C) 2005 Elsevier B.V. All rights reserved.
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