Journal
ELECTROCHEMISTRY COMMUNICATIONS
Volume 8, Issue 3, Pages 445-449Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2006.01.008
Keywords
ionic liquid; Lewis base; lithium electrochemistry; ionic conductivity
Categories
Ask authors/readers for more resources
A new Lewis-base ionic liquid (IL) based on mono-charged 1,4-diazabicyclo[2.2.2]octane (dabco) was synthesized and its thermal and electrochemical behaviour was characterized. The dabco-based IL with bis(trifluoromethanesulfonyl)amide (TFSA) anion melts at 76 degrees C when the N-substituted alkyl chain length is 2. The dabco-based IL showed a wide electrochemical window of over 4 V ranging from -3.5 to +1.5 V vs. Fc/Fc(+) and was able to deposit and strip lithium from a nickel substrate at reasonable efficiency. (c) 2006 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available