Journal
ORGANIC LETTERS
Volume 8, Issue 5, Pages 999-1001Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol060112g
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L-Pipecolinic acid derived formamides have been developed as highly efficient and enantioselective Lewis basic organocatalysts for the reduction of N-aryl imines with trichlorosilane. Catalyst 4b afforded high isolated yields (up to 98%) and enantioselectivities(up to 96%) under mild conditions with an unprecedented substrate spectrum.
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