Journal
ORGANIC LETTERS
Volume 8, Issue 5, Pages 983-986Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0600335
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Funding
- NINDS NIH HHS [NS20036, R01 NS020036-18, R01 NS020036] Funding Source: Medline
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A highly concerted strategy for the synthesis of symmetrical type-VI beta-turn mimics was formulated. A proof of concept is presented in the synthesis of a spirobicyclic peptidomimetic of Pro-Pro-Pro-NH2, compound 6. The formation of an unusual adduct that was encountered in the process also is reported. This approach is potentially general for type-VI beta-turn mimics where the i + 1 and i + 2 residues are identical.
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