Journal
ORGANIC LETTERS
Volume 8, Issue 5, Pages 883-886Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol052962m
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PtCl2 (5 mol %) is an effective catalyst for aromatization of enediynes via a C-H bond insertion of tethered alkanes. The reaction mechanism of this cyclization is proposed to involve platinum-pi-alkyne intermediates. This cyclization works not only for terminal alkynes but also for internal alkynes.
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