4.7 Article

Poly(ethylene glycol) (400) as superior solvent medium against ionic liquids for catalytic hydrogenations with PtO2

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 71, Issue 5, Pages 2196-2199

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo052604x

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Adams' catalyst in poly(ethylene glycol) (PEG) (400) has been found to be a superior solvent over the ionic liquids by severalfold in promoting the hydrogenation of various functional groups. Both the catalyst and PEG were recycled efficiently over 10 runs without loss of activity, and substrate cross contamination was not observed despite a change in the substrate four times.

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