4.8 Article

Sonoelectrochemistry of Cu2+ in the presence of cetyltrimethylammonium bromide:: Obtaining CuBr instead of copper

Journal

CHEMISTRY OF MATERIALS
Volume 18, Issue 5, Pages 1184-1189

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/cm052043q

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The sonoelectrochemistry of Cu2+ ions which yields metallic copper with surfactants such as poly-(N-vinyl-2-pyrrolidone) and poly(vinyl alcohol) or without any surfactant produced nanocrystalline CuBr (95 wt %) and 5% of metallic copper in the presence of cetyltrimethylammonium bromide. A sonoelectrochemical mechanism explaining the different behaviors for the various surfactants is proposed.

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