Journal
CHEMISTRY OF MATERIALS
Volume 18, Issue 5, Pages 1347-1353Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cm052219o
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A few types of crystalline hollow structures, crystalline carbon hollow spheres (750 nm), crystalline carbon hollow spheres with encapsulated or decorated 1-3 nm SnO2 nanoparticles, and crystalline SnO2 hollow spheres (200-300 nm) synthesized by various methods, have been evaluated for reversible Li+ storage. The experimental results showed noticeable improvements in a number of performance areas such as specific capacity, rate capability, and cyclability. The improvements could be attributed to a high degree of crystallinity, which increases the electronic conductivity, and the facile transport of Li ions in a hollow shell with nanoscale thickness, which significantly shortens the solid-state diffusion length.
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