Journal
JOURNAL OF CATALYSIS
Volume 238, Issue 2, Pages 425-429Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2006.01.010
Keywords
telomerization; isoprene; phospholene; P,N ligands; palludium; homogeneous catalysis; photochemical reactions
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2-(2-Pyridyl)-2-phospholenes are efficient ligands for the palladium-catalyzed telomerization of isoprene with diethylamine. Good selectivities for the tail-to-head or tail-to-tail aminoterpenes are achieved on optimization of the ligand substituents and of the reaction conditions, such as the nature of the catalyst precursor and of the solvent. Moreover, excellent catalytic activities are achieved oil photochemical activation or addition of acidic co-catalysts. (c) 2006 Elsevier Inc. All rights reserved.
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