4.8 Article

Gold (I) and (III) catalyze Suzuki cross-coupling and homocoupling, respectively

Journal

JOURNAL OF CATALYSIS
Volume 238, Issue 2, Pages 497-501

Publisher

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2005.12.015

Keywords

gold catalysts for carbon-carbon bond formation; gold(I) catalysts for Suzuki cross-coupling; gold(III) catalysts for homocoupling C-C formation

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Trinuclear triphenylphosphine 1,2Au(I) complexes with the [N,N,0,]-tridentate unsymmetrical Schiff bases (1,2) catalyze the Suzuki cross-coupling reaction to afford nonsymmetrical biaryls in good yields, whereas the 1,2Au(111) complexes give only arylboronic homocoupling (c) 2005 Elsevier Inc. All rights reserved.

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