Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 124, Issue 10, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.2171967
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We present laboratory studies of the radiolysis of pure (97%) solid H2O2 films by 50 keV H+ at 17 K. Using UV-visible and infrared reflectance spectroscopies, a quartz-crystal microbalance, and a mass spectrometer, we measured the absolute concentrations of the H2O, O-2, H2O2, and O-3 products as a function of irradiation fluence. Ozone was identified by both UV and infrared spectroscopies and O-2 from its forbidden transition in the infrared at 1550 cm(-1). From the measurements we derive radiation yields, which we find to be particularly high for the decomposition of hydrogen peroxide; this can be explained by the occurrence of a chemical chain reaction.
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