Journal
JOURNAL OF PHYSICAL CHEMISTRY A
Volume 110, Issue 10, Pages 3383-3387Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp055976i
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We have investigated the primary photodynamics of the aqueous formate anion using femtosecond transient absorption spectroscopy. The formate anions are excited at 200 nm, and the resulting products are probed in the region 200-650 nm. The ultraviolet part of the transient spectrum compares favorably with that of O-(aq). However, its counter radical, HCO(aq), is not observed. In the visible region hydrated electrons are observed. The electrons are produced from photodetachment of the formate anions and from two-photon ionization of water.
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