Journal
ORGANIC LETTERS
Volume 8, Issue 6, Pages 1121-1124Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol053110p
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Funding
- NIGMS NIH HHS [R01 GM3540, R01 GM063540-05, R01 GM063540] Funding Source: Medline
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Pd[(-)-sparteine]Cl-2 catalyzes the formation of dialkyl acetals from styrene derivatives with Markovnikov regioselectivity. The substrate scope of this reaction has been investigated, and initial mechanistic studies indicate that the reaction proceeds through an enol ether intermediate and a Pd-hydride.
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