4.4 Article

PhI-catalyzed α-tosyloxylation of ketones with m-chloroperbenzoic acid and p-toluenesulfonic acid

Journal

SYNLETT
Volume -, Issue 5, Pages 798-800

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-2006-933120

Keywords

iodobenzene; alpha-tosyloxyketones; ketones; m-chloroperbenzoic acid; p-toluenesulfonic acid; catalysts

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Various alpha-tosyloxyketones were efficiently prepared in high yields from the reaction of ketones with m-chloroperbenzoic acid and p-toluenesulfonic acid in the presence of a catalytic amount of iodobenzene at warming temperature.

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