Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 71, Issue 6, Pages 2313-2319Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo052429k
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[GRAPHICS] The zwitterion formed by the reaction of dimethoxycarbene and DMAD adds efficiently to one of the carbonyl groups of 1,2-dicarbonyl compounds and anhydrides to generate dihydrofurans and spirodihydrofurans in good yields. In many cases, the carbene inserts into the C-C bond of the dione to yield masked vicinal tricarbonyl systems.
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