Journal
INORGANIC CHEMISTRY
Volume 45, Issue 6, Pages 2397-2399Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic060049r
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H-2, N-2, CO, and CO2 are readily incorporated in the porous, 3D sodalitic frameworks of coordination polymers of the [ML2](n) type, with M = Pd-II or Cu-II and HL = 2-hydroxypyrimidine or 4-hydroxypyrimidine. The metal ion and ligand functionalization modulate their sorption properties, making these materials suitable for gas storage and separation purposes.
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